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1.
PLoS One ; 16(9): e0255391, 2021.
Artigo em Inglês | MEDLINE | ID: mdl-34570763

RESUMO

Landfills provide seasonally reliable food resources to many bird species, including those perceived to be pest or invasive species. However, landfills often contain multiple habitat types that could attract diverse species, including those of conservation concern. To date, little is known about the characteristics and composition of bird communities at landfills relative to local and regional pools. Here we used the community science database eBird to extract avian species occurrence data at landfills across the US. We compared species richness and community similarity across space in comparison to similarly-sampled reference sites, and further quantified taxonomic and dietary traits of bird communities at landfills. While landfills harbored marginally lower species richness than reference sites (respective medians of 144 vs 160), landfill community composition, and its turnover across space, were similar to reference sites. Consistent with active waste disposal areas attracting birds, species feeding at higher trophic levels, especially gulls, were more frequently observed at landfills than reference sites. However, habitat specialists including two declining grassland species, Eastern Meadowlark (Sturnella magna) and Savannah Sparrow (Passerculus sandwichensis), as well as migratory waterfowl, were more frequently encountered at landfills than reference sites. Together, these results suggest that landfills harbor comparable avian diversity to neighboring sites, and that habitats contained within landfill sites can support species of conservation concern. As covered landfills are rarely developed or forested, management of wetlands and grasslands at these sites represents an opportunity for conservation.


Assuntos
Biodiversidade , Aves/classificação , Aves/fisiologia , Ecossistema , Dinâmica Populacional , Instalações de Eliminação de Resíduos/estatística & dados numéricos , Áreas Alagadas , Animais , Conservação dos Recursos Naturais
2.
PLoS One ; 16(2): e0246334, 2021.
Artigo em Inglês | MEDLINE | ID: mdl-33635880

RESUMO

A critical examination of the US Environmental Protection Agency's (US EPA's) Greenhouse Gas Reporting Program (GHGRP) database provided an opportunity for the largest evaluation to date of landfilled waste decomposition kinetics with respect to different US climate regimes. In this paper, 5-8 years of annual methane collection data from 114 closed landfills located in 29 states were used to estimate site-specific waste decay rates (k) and methane collection potentials (Lc). These sites account for approximately 9% of all landfills required to report GHG emissions to the US EPA annually. The mean methane collection potential (Lc) for the sites located in regions with less than 635 mm (25 in) annual rainfall was significantly (p<0.002) lower than the mean methane collection potential of the sites located in regions with more than 635 mm (25 in) annual precipitation (49 and 73 m3 methane Mg-1 waste, respectively). This finding suggests that a fraction of the in-place biodegradable waste may not be decomposing, potentially due to a lack of adequate moisture content of landfills located in arid regions. The results of this evaluation offer insight that challenges assumptions of the traditional landfill methane estimation approach, especially in arid climates, that all methane corresponding to the total methane generation potential of the buried solid waste will be produced. Decay rates showed a significant correlation with annual precipitation, with an average k of 0.043 year-1 for arid regions (< 508 mm (20 in) year-1), 0.074 year-1 for regions with 508-1,016 mm (20-40 in) annual precipitation, and 0.09 year-1 in wet regions (> 1,016 mm (40 in) year-1). The data suggest that waste is decaying faster than the model default values, which in turn suggests that a larger fraction of methane is produced during a landfill's operating life (relative to post-closure).


Assuntos
Mudança Climática , Gases de Efeito Estufa , Metano/biossíntese , Instalações de Eliminação de Resíduos , Mudança Climática/estatística & dados numéricos , Gases de Efeito Estufa/efeitos adversos , Modelos Estatísticos , Estados Unidos , Instalações de Eliminação de Resíduos/estatística & dados numéricos , Tempo (Meteorologia)
3.
J Environ Public Health ; 2020: 3780431, 2020.
Artigo em Inglês | MEDLINE | ID: mdl-32184833

RESUMO

This study deals with the occupational health and safety of valuable and recyclable waste collectors (called scavengers) in the Gaza Strip, Palestine. The analytical descriptive approach was used in this study to achieve this goal. Waste pickers in the study area are working informally at existing dumpsites, solid waste transfer stations, landfills, and community streets' bins areas. A sample of 301 scavengers was surveyed filling a structured questionnaire designed for this purpose, during individual interviews. In addition, interviews with key Palestinian officials in the Gaza Strip have been conducted to provide accurate data and comprehensive information regarding waste pickers activities. The results showed that the occupational health and safety of the waste pickers is in constant deterioration mainly due to the informal nature of their work. The waste pickers are reportedly suffering in the current situation and the majority has no access to potable water, sanitation, and hygienically appropriate place to sleep and have meals. None of them has ever received occupational health and safety training. The study recommends that local decision makers should uptake short-term and long-term measures in waste management sector both aiming at improving this vulnerable social group's health and safety life status.


Assuntos
Saúde Ocupacional/estatística & dados numéricos , Reciclagem , Eliminação de Resíduos , Adolescente , Adulto , Criança , Humanos , Masculino , Pessoa de Meia-Idade , Oriente Médio/epidemiologia , Inquéritos e Questionários , Populações Vulneráveis/estatística & dados numéricos , Instalações de Eliminação de Resíduos/estatística & dados numéricos , Gerenciamento de Resíduos/métodos , Gerenciamento de Resíduos/estatística & dados numéricos , Adulto Jovem
4.
Environ Sci Pollut Res Int ; 27(4): 4528-4535, 2020 Feb.
Artigo em Inglês | MEDLINE | ID: mdl-31788730

RESUMO

Landfill stabilization contributes to the safe operation and maintenance of landfills. This study used a simulated aerobic bioreactor landfill to investigate the impact of different compaction densities on its stabilization to provide a basis for optimal parameter selection during landfill design. Samples of municipal solid waste were tested with compaction densities of 450, 500, 550, 600, and 650 kg/m3 during the experiment. The optimum compaction density was obtained by periodically monitoring the temperature of the waste pile, the water quality of leachate, and the composition of the waste. The impacts of waste compaction density on waste pile temperature and leachate were investigated and coupled with the analysis of waste composition to discuss the possible reaction mechanism. Results showed that the most complete waste degradation occurred at 550 kg/m3 compaction density, which was effective at accelerating stabilization of the simulated aerobic bioreactor landfill. Limitations of the experiment are given to lay foundations for further study.


Assuntos
Eliminação de Resíduos , Poluentes Químicos da Água , Reatores Biológicos/estatística & dados numéricos , Eliminação de Resíduos/métodos , Resíduos Sólidos , Temperatura , Instalações de Eliminação de Resíduos/estatística & dados numéricos
5.
J Occup Environ Med ; 61 Suppl 12: S45-S54, 2019 12.
Artigo em Inglês | MEDLINE | ID: mdl-31800450

RESUMO

OBJECTIVE: The potential health risks of deployment to sites with open burn pits remain poorly understood, in part, because personal exposure monitoring was not performed. Here, we investigated whether postdeployment serum samples contain biomarkers associated with exposure to burn pits. METHODS: A total of 237 biomarkers were measured in 800 serum samples from deployed and never-deployed subjects. We used a regression model and a supervised vector machine to identify serum biomarkers with significant associations with exposures and deployment. RESULTS: We identified 101 serum biomarkers associated with polycyclic aromatic hydrocarbons, dioxins or furans, and 54 biomarkers associated with deployment. Twenty-six of these biomarkers were shared in common by the exposure and deployment groups. CONCLUSIONS: We identify a potential signature of exposure to open burn pits, and provide a framework for using postexposure sera to identify exposures when contemporaneous monitoring was inadequate.


Assuntos
Poluentes Atmosféricos/sangue , Exposição por Inalação/análise , Militares/estatística & dados numéricos , Campanha Afegã de 2001- , Poluentes Atmosféricos/efeitos adversos , Biomarcadores/sangue , Dioxinas/efeitos adversos , Dioxinas/sangue , Feminino , Furanos/efeitos adversos , Furanos/sangue , Humanos , Incineração/estatística & dados numéricos , Exposição por Inalação/efeitos adversos , Exposição por Inalação/normas , Guerra do Iraque 2003-2011 , Aprendizado de Máquina , Masculino , Espectrometria de Massas , MicroRNAs/sangue , Hidrocarbonetos Policíclicos Aromáticos/efeitos adversos , Hidrocarbonetos Policíclicos Aromáticos/sangue , Estados Unidos , Instalações de Eliminação de Resíduos/estatística & dados numéricos
6.
Artigo em Inglês | MEDLINE | ID: mdl-31590350

RESUMO

This study determined the presence of important antibiotic-resistant bacteria in selected environments in Thailand, including wastewater samples from 60 hospitals; washed fluid, leachate, flies, cockroaches, and rats collected from five open markets; washed fluid from garbage trucks; and stabilized leachate from a landfill facility. At least one type of antibiotic-resistant bacteria was isolated from all samples of influent fluid before treatment in hospitals, from wastewater treatment tank content in hospitals, and from 15% of effluent fluid samples after treatment with chlorine prior to draining it into a public water source. Antibiotic-resistant bacteria were recovered from 80% of washed market fluid samples, 60% of market leachate samples, all fly samples, 80% of cockroach samples, and all samples of intestinal content of rats collected from the open markets. Antibiotic-resistant bacteria were recovered from all samples from the landfill. Extended-spectrum beta-lactamase (ESBL)-producing Escherichia coli and/or Klebsiella pneumoniae were the most common antibiotic-resistant bacteria recovered from all types of samples, followed by carbapenem-resistant E. coli and/or K. pneumoniae. Colistin-resistant Enterobacteriaceae, carbapenem-resistant Psuedomonas aeruginosa, carbapenem-resistant Acinetobacter baumannii, colistin-resistant Enterobacteriaceae, vancomycin-resistant Enterococci, and methicillin-resistant S. aureus were less common. These findings suggest extensive contamination by antibiotic-resistant bacteria in hospital and community environment in Thailand.


Assuntos
Bactérias/isolamento & purificação , Farmacorresistência Bacteriana , Animais , Hospitais/estatística & dados numéricos , Humanos , Testes de Sensibilidade Microbiana , Ratos , Tailândia , Instalações de Eliminação de Resíduos/estatística & dados numéricos , beta-Lactamases
7.
Mar Pollut Bull ; 149: 110558, 2019 Dec.
Artigo em Inglês | MEDLINE | ID: mdl-31542605

RESUMO

The marine environment is constantly being impacted by anthropogenic activities. Nowadays, microplastics (MPs) representing one of the most deleterious material among of all substances and material from anthropogenic origin. The Microplastics (MPs) are particles smaller than 5 mm. This study presents information on abundance, distribution, type and colour of microplastics in the bottom sediments of the continental Shelf of Rio de Janeiro State. This area is strongly impacted due to its location in front of one of the most polluted coastal bays in the Brazilian Coastline. It receives untreated sewage from an Ipanema Beach submarine emissary and also a great amount of sediments dredged from Rio de Janeiro Harbour, which strongly influences the distribution of MPs in the area. The analyses detected the presence of MP in 100% of the samples, composed mainly by secondary microplastics, and almost 50% were fibers, followed by plastic films, plastic fragments and pellets. Based on the nature of the sources of the MP, a great variety of colours was shown, dominated by four main colours: blue, white, transparent, and black, this pattern could potentially increase their bioavailability due to resemblance to prey items, especially to visual raptorial species.


Assuntos
Baías/química , Monitoramento Ambiental , Sedimentos Geológicos/química , Microplásticos/análise , Instalações de Eliminação de Resíduos/estatística & dados numéricos , Poluentes Químicos da Água/análise , Brasil , Meio Ambiente , Esgotos/análise
8.
Environ Sci Pollut Res Int ; 26(35): 35325-35339, 2019 Dec.
Artigo em Inglês | MEDLINE | ID: mdl-31044377

RESUMO

Landfill site's selection represents a complicated process due to the large number of variables to be adopted. In this study, an arid area (Babylon Governorate as a case study) was selected. It is located in the middle region of Iraq. In this area, the landfills do not satisfy the required international criteria. Fifteen of the most significant criteria were selected for this purpose. For suitable weight for each criterion, the multi-criteria decision-making (MCDM) methods were applied. These methods are AHP and RSW. In the GIS software 10.5, the raster maps of the chosen criterion were arranged and analyzed. The method of change detection was implemented to determine the matching pixels and non-matching pixels. The final results showed that there are two candidate locations for landfills for each district in the governorate (ten sites). The areas of the selected sites were sufficient to contain the cumulative quantity of solid waste from 2020 until 2030.


Assuntos
Eliminação de Resíduos/métodos , Resíduos Sólidos/análise , Instalações de Eliminação de Resíduos/estatística & dados numéricos , Tomada de Decisões , Sistemas de Informação Geográfica , Iraque
9.
Environ Pollut ; 248: 1036-1045, 2019 May.
Artigo em Inglês | MEDLINE | ID: mdl-31091636

RESUMO

Electronic waste (e-waste) has emerged as a global environmental problem because of its massive production volume and un-structured management policy. Since the rate of e-waste accumulation is startling and the combinatorial effects of toxicants are complex, we have investigated six phthalic acid esters (PAEs), bis (2-ethylhexyl) adipate (DEHA)), bisphenol A (BPA), sixteen polycyclic aromatic hydrocarbons (PAHs) and eight heavy metals (HMs) in the surface soil of e-waste recycling workshops and nearby open dumpsites in four metropolitan cities of India viz., New Delhi (north), Kolkata (east), Mumbai (west) and Chennai (south). Average concentration of ∑16PAHs (1259 ng/g), ∑6PAEs (396 ng/g), BPA (140 ng/g) and ∑8HM (1288 mg/kg) in the informal e-waste recycling sites were higher than ∑16PAHs (1029 ng/g), ∑6PAEs (93 ng/g), BPA (121 ng/g) and ∑8HM (675 mg/kg) in dumpsites. Almost 50-90% of BPA, bis (2-ethylhexyl) phthalate (DEHP), ∑7carcPAHs and copper (Cu) were from e-waste sites predominantly from metal recovery sites (EWR). Extensive combustion of e-waste particularly in the EWR sites at New Moore market and Pudupet in Chennai and Wire Lane, Kurla of Mumbai can explain the segregation of diethyl phthalate (DEP), benzyl butyl phthalate (BBP) and carcinogenic PAHs in the first principal component (PC-1). Copper and lead along with highly abundant plasticizers like DEHP, dibutyl phthalate (DBP) and BPA were loaded in PC-2. Combined impact of burning the plastic cables in e-waste and acid leaching process especially at Mandoli in New Delhi might have driven this result. Loading of chrysene, DEHA and low molecular weight (LMW) PAHs mostly in dumpsite soil might have resulted from incomplete combustion of dumped e-waste. Copper was found to exhibit the highest pollution estimated by geo-accumulation index (Igeo). Maximum estimated carcinogenic risk for adults via dermal contact was due to copper, followed by chromium, lead and nickel.


Assuntos
Compostos Benzidrílicos/análise , Resíduo Eletrônico/análise , Metais Pesados/análise , Fenóis/análise , Plastificantes/análise , Hidrocarbonetos Policíclicos Aromáticos/análise , Poluentes do Solo/análise , Instalações de Eliminação de Resíduos/estatística & dados numéricos , Cidades , Dibutilftalato/análise , Ésteres/análise , Índia , Ácidos Ftálicos/análise , Reciclagem , Solo/química
10.
Environ Sci Pollut Res Int ; 26(35): 35317-35324, 2019 Dec.
Artigo em Inglês | MEDLINE | ID: mdl-30854620

RESUMO

In the whole territory of Castilla y León (Spain), there are currently more than 2000 waste dumps that will be restored through a novel programme in the period 2017-2019 with an investment of more than 10 M€. Castilla y León regional government is currently implementing this programme in the province of Valladolid for the environmental recovery of areas heavily degraded by the deposit of inert waste, which entails the restoration of illegal dumps in the province bigger than 1000 m2, a total of 133. The programme also includes the implementation of an alternative and legal system for the management of construction and demolition waste, amongst other waste streams. The sealing of landfills and tailings is encompassed within the actions that the regional government is developing in the field of integrated management of waste for their prevention, recovery, recycling and disposal in all the provinces of the community, framed within the line established in the 7th Environmental Action Programme of the European Union. The situation of illegal deposits must be corrected both through direct situations on the affected areas and through measures aimed at ensuring proper management of construction and demolition waste and pruning. This paper shows the first results obtained after the implementation of this regional initiative with the focus set on the description of the implemented waste management programme. The programme provided 2518 services in 2017 managing 6000 t of waste which, without the implementation of this programme, would probably have ended up in illegal dumps. These waste streams included debris (33%), discarded appliances (45%) and pruning (22%). The costs associated with the management of these streams were 25.53 €/t debris, 183.16 €/t appliances and 162.40 €/t pruning.


Assuntos
Reciclagem/métodos , Gerenciamento de Resíduos/métodos , Custos e Análise de Custo , União Europeia , Eliminação de Resíduos , Espanha , Instalações de Eliminação de Resíduos/estatística & dados numéricos , Gerenciamento de Resíduos/economia
11.
Artigo em Inglês | MEDLINE | ID: mdl-30596317

RESUMO

This study aims to modify the SINTACS and DRASTIC models with a land-use (LU) layer and compares the modified-DRASTIC, modified-SINTACS and SI methods for groundwater vulnerability assessment (GVA) in the southern Tehran aquifer, Iran. Single parameter sensitivity analysis (SPSA) served to determine the most significant parameters for the modified-DRASTIC, modified-SINTACS and SI approaches, and to revise model weights from "theoretical" to "effective." The inherent implementation of LU in the SI model may explain its better performance compared to unenhanced versions of DRASTIC and SINTACS models. Validation of all models, using nitrate concentrations from 20 wells within the study area, showed the modified-SINTACS model to outperform other models. The SPSA showed that the vadose zone and LU strongly influenced the modified-DRASTIC and modified-SINTACS models, while SI was strongly influenced by aquifer media and LU. To improve performance, models were implemented using "effective" instead of "theoretical" weights. Model robustness was assessed using nitrate concentrations in the aquifer and the outcomes confirmed the positive impact of using "effective" versus "theoretical" weights in the models. Modified-SINTACS showed the strongest correlation between nitrate and the vulnerability index (coefficient of determination = 0.75). Application of the modified-SINTACS while using "effective" weights, led to the conclusion that 19.6%, 55.2%, 23.4%, and 1.6% of the study area housed very high, high, moderate and low vulnerability zones, respectively.


Assuntos
Monitoramento Ambiental/métodos , Água Subterrânea/análise , Modelos Teóricos , Poluição da Água/análise , Atividades Humanas/estatística & dados numéricos , Humanos , Resíduos Industriais/análise , Irã (Geográfico)/epidemiologia , Instalações Industriais e de Manufatura/estatística & dados numéricos , Nitratos/análise , Campos de Petróleo e Gás , Medição de Risco , Instalações de Eliminação de Resíduos/estatística & dados numéricos , Poluentes Químicos da Água/análise
12.
Chemosphere ; 218: 836-844, 2019 Mar.
Artigo em Inglês | MEDLINE | ID: mdl-30508802

RESUMO

With the phasing out of brominated flame retardants, organophosphate flame retardants (OPFRs) have been widely used and further detected in multiple environmental media. However, municipal landfill leachates, an important source of contamination of OPFRs to aquatic environment, have not been fully understood, especially in a developing country like China. Thus, the occurrence, aqueous removal efficiency, environmental emission, and risk assessment of 10 OPFRs were investigated in leachates from six municipal landfills across China. The results indicated that except triethyl phosphate (TEP), the remaining 9 OPFRs were detected in both raw and final leachates with different frequencies higher than 33.3%. The range of total concentrations of OPFRs (ΣOPFRs) across China was 29.0-437 and 0.652-32.4 µg L-1 in raw and final leachates, respectively. Tris(2-chloroethyl) phosphate (TCEP) was the dominant species and accounted for 78.5% and 85.8% of average ΣOPFR concentration in raw and final leachates, respectively. This may be because TCEP is the most prevalently used OPFR in China. The overall aqueous removal efficiency of ΣOPFRs across China ranged from 57.7% to 99.8%. Tris(2-butoxyethyl) phosphate was the most removed species (98.8%), whereas TCEP was the least removed species (91.5%). The annual emissions of ΣOPFRs discharged into the aquatic environment from municipal landfills across China were estimated to be between 170 and 7094 g. Further risk assessment based on risk quotient values in the final leachates showed that most OPFRs posed negligible risk except TCEP (medium and high risk) and tributyl phosphate (medium risk).


Assuntos
Retardadores de Chama/análise , Organofosfatos/análise , Poluentes Químicos da Água/análise , China , Poluição Ambiental , Recuperação e Remediação Ambiental , Retardadores de Chama/isolamento & purificação , Retardadores de Chama/farmacologia , Organofosfatos/isolamento & purificação , Organofosfatos/farmacologia , Medição de Risco , Instalações de Eliminação de Resíduos/estatística & dados numéricos , Poluentes Químicos da Água/isolamento & purificação , Poluentes Químicos da Água/farmacologia
13.
Artigo em Inglês | MEDLINE | ID: mdl-30577663

RESUMO

The municipal solid waste (MSW) landfill in Vientiane, Laos, which receives > 300 tons of waste daily, of which approximately 50% is organic matter, has caused serious environmental problems. This study was conducted to investigate the accumulated levels of heavy metals (HMs) (cadmium (Cd), chromium (Cr), copper (Cu), nickel (Ni), lead (Pb), and zinc (Zn)) in water (surface and groundwater), soil, and plants between dry and wet seasons according to the standards of the Agreement on the National Environmental Standards of Laos (ANESs), Dutch Pollutant Standards (DPSs), and the World Health Organization (WHO), respectively. Although no impact of pollution on the surface water was observed, the levels of Cr and Pb in the groundwater significantly exceeded the basics of ANESs and WHO in both seasons. The pollution caused by Cd and Cu reached the eco-toxicological risk level in the landfill soils and its vicinity. The vegetable Ipomoea aquatica, which is consumed by the nearby villagers, was seriously contaminated by Cr, Pb, Cu, and Zn, as the accumulation of these toxic metals was elevated to much greater levels as compared to the WHO standards. For the grass Pennisetum purpureum (elephant grass), the quantities of HMs in all plant parts were extreme, perhaps due to the deeper growth of its rhizome than I. aquatica. This study is the first to warn of serious HM pollution occurring in the water, soil, and plants in the MSW landfill of Vientiane, Laos, which requires urgent phytoremediation. The indication of what sources from the MSW principally cause the pollution of HMs is needed to help reduce the toxicological risks on Lao residents and the environment in Vientiane as well.


Assuntos
Monitoramento Ambiental , Poluentes Ambientais/análise , Metais Pesados/análise , Plantas/metabolismo , Resíduos Sólidos , Instalações de Eliminação de Resíduos/estatística & dados numéricos , Poluentes Ambientais/metabolismo , Poluentes Ambientais/normas , Contaminação de Alimentos/análise , Laos , Metais Pesados/metabolismo , Metais Pesados/normas , Solo/química , Resíduos Sólidos/análise , Instalações de Eliminação de Resíduos/normas , Água/química
14.
Artigo em Inglês | MEDLINE | ID: mdl-30463245

RESUMO

Achieving high efficiency of biological waste treatment in mechanical⁻biological treatment (MBT) plants requires reliable methods for measuring the degree of biodegradation of organic substances. For this purpose, several physical, chemical, and biological indices are used. This paper presents respirometric activity (AT4), biogas potential (GB21), total and dissolved organic carbon (TOC and DOC, respectively), and loss on ignition (LOI) values, as well as the correlations between the indices selected for stabilized waste produced in 18 MBT plants in Poland, which use various technologies for biological processing of the organic fraction of municipal solid waste. The study confirms that there is a linear relationship between AT4 and GB21 for stabilized waste produced in MBT plants, regardless of the waste treatment technology used. It has also been found that there is a linear relationship between AT4 and the concentration of dissolved carbon in water extract from stabilized waste. This indicates that DOC can be used for monitoring the organic matter stabilization process in mechanical⁻biological waste treatment plants. Its advantage is a shorter time needed for measurements in comparison to AT4 and GB21 tests.


Assuntos
Biodegradação Ambiental , Compostagem , Eliminação de Resíduos/estatística & dados numéricos , Resíduos Sólidos/análise , Instalações de Eliminação de Resíduos/estatística & dados numéricos , Biocombustíveis/análise , Carbono/análise , Compostos Orgânicos/metabolismo , Oxigênio/análise , Polônia
15.
Artigo em Inglês | MEDLINE | ID: mdl-29899229

RESUMO

Mercury is a neurotoxin, with certain organic forms of the element being particularly harmful to humans. The Minamata Convention was adopted to reduce the intentional use and emission of mercury. Because mercury is an element, it cannot be decomposed. Mercury-containing products and mercury used for various processes will eventually enter the waste stream, and landfill sites will become a mercury sink. While landfill sites can be a source of mercury pollution, the behavior of mercury in solid waste within a landfill site is still not fully understood. The purpose of this study was to determine the depth profile of mercury, the levels of methyl mercury (MeHg), and the factors controlling methylation in an old landfill site that received waste for over 30 years. Three sampling cores were selected, and boring sampling was conducted to a maximum depth of 18 m, which reached the bottom layer of the landfill. Total mercury (THg) and MeHg were measured in the samples to determine the characteristics of mercury at different depths. Bacterial species were identified by 16S rRNA amplification and sequencing, because the methylation process is promoted by a series of genes. It was found that the THg concentration was 19⁻975 ng/g, with a geometric mean of 298 ng/g, which was slightly less than the 400 ng/g concentration recorded 30 years previously. In some samples, MeHg accounted for up to 15⁻20% of THg, which is far greater than the general level in soils and sediments, although the source of MeHg was unclear. The genetic data indicated that hgcA was present mostly in the upper and lower layers of the three cores, merA was almost as much as hgcA, while the level of merB was hundreds of times less than those of the other two genes. A significant correlation was found between THg and MeHg, as well as between MeHg and MeHg/THg. In addition, a negative correlation was found between THg and merA. The coexistence of the three genes indicated that both methylation and demethylation processes could occur, but the lack of merB was a barrier for demethylation.


Assuntos
Mercúrio/análise , Mercúrio/química , Compostos de Metilmercúrio/análise , Instalações de Eliminação de Resíduos/estatística & dados numéricos , Monitoramento Ambiental , Poluição Ambiental , Japão , Metilação , RNA Ribossômico 16S
16.
J Environ Radioact ; 190-191: 10-19, 2018 Oct.
Artigo em Inglês | MEDLINE | ID: mdl-29734123

RESUMO

In the present paper, deterministic as well as first- and second-order probabilistic biosphere modeling approaches are compared. Furthermore, the sensitivity of the influence of the probability distribution function shape (empirical distribution functions and fitted lognormal probability functions) representing the aleatory uncertainty (also called variability) of a radioecological model parameter as well as the role of interacting parameters are studied. Differences in the shape of the output distributions for the biosphere dose conversion factor from first-order Monte Carlo uncertainty analysis using empirical and fitted lognormal distribution functions for input parameters suggest that a lognormal approximation is possibly not always an adequate representation of the aleatory uncertainty of a radioecological parameter. Concerning the comparison of the impact of aleatory and epistemic parameter uncertainty on the biosphere dose conversion factor, the latter here is described using uncertain moments (mean, variance) while the distribution itself represents the aleatory uncertainty of the parameter. From the results obtained, the solution space of second-order Monte Carlo simulation is much larger than that from first-order Monte Carlo simulation. Therefore, the influence of epistemic uncertainty of a radioecological parameter on the output result is much larger than that one caused by its aleatory uncertainty. Parameter interactions are only of significant influence in the upper percentiles of the distribution of results as well as only in the region of the upper percentiles of the model parameters.


Assuntos
Modelos Químicos , Modelos Estatísticos , Resíduos Radioativos/estatística & dados numéricos , Geologia , Funções Verossimilhança , Método de Monte Carlo , Medição de Risco/métodos , Incerteza , Instalações de Eliminação de Resíduos/estatística & dados numéricos
17.
Sci Total Environ ; 634: 509-515, 2018 Sep 01.
Artigo em Inglês | MEDLINE | ID: mdl-29631140

RESUMO

To assess the impacts of e-waste regulations on environmental pollution, we built on a previous study from 2010 to investigate the levels and human dietary exposure of halogenated flame retardants (HFRs) in free-range chicken eggs from Baihe village in 2013 and 2016. The concentrations of PBDEs, PBBs, HBCDs, and DBDPE showed a significant decrease (p<0.05) from 2010 to 2013/2016, suggesting the efficacy of regulatory policies. The relative contribution of BDE209 were higher in 2013 and 2016 than in 2010, accounting for 67.8%, 61.4%, and 27.7%, respectively. The concentration ratios of PBB209:PBB153 were much lower in 2013 (1.51) and 2016 (1.32) than in 2010 (29.5). These observed different profiles likely due to the different environmental behaviors of HFRs (e.g. the different atmospheric migration abilities of PBDE congeners and degradation of PBB209). Our exposure estimates suggested high dietary intake of HFRs via home-produced eggs. As for PBDEs, considering the worst situation (highly polluted eggs were consumed), the margin of exposure (MOE) of BDE99 for both adults and children were 1.5 and 0.3 in 2013, and 1.1 and 0.2 in 2016, respectively, which were below 2.5. According to the CONTAM panel, an MOE larger than 2.5 indicates no health concern. Therefore, these MOE values represent a significant potential health concern due to the adverse impacts of PBDEs on human neurodevelopment and fertility.


Assuntos
Exposição Dietética/estatística & dados numéricos , Ovos/análise , Resíduo Eletrônico/análise , Poluentes Ambientais/análise , Retardadores de Chama/análise , Instalações de Eliminação de Resíduos/estatística & dados numéricos , Adulto , Animais , Galinhas , Criança , China , Exposição Dietética/análise , Monitoramento Ambiental , Humanos
18.
Int J Health Geogr ; 17(1): 8, 2018 03 20.
Artigo em Inglês | MEDLINE | ID: mdl-29558944

RESUMO

BACKGROUND: Millions of people worldwide are exposed to deadly infectious diseases on a regular basis. Breaking news of the Zika outbreak for instance, made it to the main media titles internationally. Perceiving disease risks motivate people to adapt their behavior toward a safer and more protective lifestyle. Computational science is instrumental in exploring patterns of disease spread emerging from many individual decisions and interactions among agents and their environment by means of agent-based models. Yet, current disease models rarely consider simulating dynamics in risk perception and its impact on the adaptive protective behavior. Social sciences offer insights into individual risk perception and corresponding protective actions, while machine learning provides algorithms and methods to capture these learning processes. This article presents an innovative approach to extend agent-based disease models by capturing behavioral aspects of decision-making in a risky context using machine learning techniques. We illustrate it with a case of cholera in Kumasi, Ghana, accounting for spatial and social risk factors that affect intelligent behavior and corresponding disease incidents. The results of computational experiments comparing intelligent with zero-intelligent representations of agents in a spatial disease agent-based model are discussed. METHODS: We present a spatial disease agent-based model (ABM) with agents' behavior grounded in Protection Motivation Theory. Spatial and temporal patterns of disease diffusion among zero-intelligent agents are compared to those produced by a population of intelligent agents. Two Bayesian Networks (BNs) designed and coded using R and are further integrated with the NetLogo-based Cholera ABM. The first is a one-tier BN1 (only risk perception), the second is a two-tier BN2 (risk and coping behavior). RESULTS: We run three experiments (zero-intelligent agents, BN1 intelligence and BN2 intelligence) and report the results per experiment in terms of several macro metrics of interest: an epidemic curve, a risk perception curve, and a distribution of different types of coping strategies over time. CONCLUSIONS: Our results emphasize the importance of integrating behavioral aspects of decision making under risk into spatial disease ABMs using machine learning algorithms. This is especially relevant when studying cumulative impacts of behavioral changes and possible intervention strategies.


Assuntos
Cólera/epidemiologia , Comportamentos Relacionados com a Saúde , Aprendizado de Máquina , Análise Espacial , Algoritmos , Inteligência Artificial/estatística & dados numéricos , Teorema de Bayes , Cólera/diagnóstico , Cólera/prevenção & controle , Doenças Transmissíveis/diagnóstico , Doenças Transmissíveis/epidemiologia , Gana/epidemiologia , Humanos , Aprendizado de Máquina/estatística & dados numéricos , Fatores de Risco , Instalações de Eliminação de Resíduos/estatística & dados numéricos
19.
Arch Environ Occup Health ; 73(2): 107-114, 2018 03 04.
Artigo em Inglês | MEDLINE | ID: mdl-28406366

RESUMO

Payatas landfill site is one of the major dumpsites in the Philippines. In this study, the landfill was evaluated regarding the presence and concentration of pathogenic bacterial aerosols through culture and molecular techniques. Bioaerosols are biological airborne particles that may or may not cause diseases. Active sampling was done using MAS-100 Air Sampler from both indoor and outdoor locations. To test the accuracy of the culture method, those that were presumptively identified as Staphylococcus aureus and Klebsiella pneumoniae were subjected to molecular analysis using 16s rRNA sequencing, and as a result, they were identified as different species. The exposure assessment done by interview showed matches among prevalent diseases. The results of this study can be used as a basis for creating standards and regulations for workers' and residents' safety and health in the landfill site.


Assuntos
Aerossóis/análise , Microbiologia do Ar , Bactérias/isolamento & purificação , Monitoramento Ambiental/métodos , Exposição Ocupacional/estatística & dados numéricos , Instalações de Eliminação de Resíduos/estatística & dados numéricos , Bacillus subtilis/genética , Bacillus subtilis/isolamento & purificação , Bactérias/genética , Contagem de Colônia Microbiana , Klebsiella pneumoniae/genética , Klebsiella pneumoniae/isolamento & purificação , Filipinas , RNA Bacteriano/análise , RNA Ribossômico 16S/análise , Risco , Análise de Sequência de RNA , Staphylococcus aureus/genética , Staphylococcus aureus/isolamento & purificação
20.
Waste Manag Res ; 35(11): 1129-1136, 2017 Nov.
Artigo em Inglês | MEDLINE | ID: mdl-28828932

RESUMO

This research was undertaken to estimate the energy potential of municipal solid waste (MSW) disposed over the past 15 years in an unsecured landfill located in Okhla, Delhi, India. The research collected a total of 98 samples from various depths and locations, which were analyzed for physico-chemical characterization. Multiple regression models for estimating the energy content of the disposed MSW were developed to predict average gross calorific value (GCV) and net calorific value (NCV). Forward entry regression was applied to identify the variables that contributed significantly to the regression. Thus, 4-parametric models and 2-parametric models were developed for predicting both average GCV and NCV of the disposed MSW. The developed models gave a reasonably good prediction of the energy content of MSW. Both the models gave low values of average absolute relative error and high values of correlation coefficient. It was found that the 2-parametric models exhibited nearly the same prediction ability with less measurable dimensions as the 4-parametric models. These models are unique and the research is a pioneering effort since apart from being the only models based on physico-chemical characteristics of disposed MSW to be reported, they also incorporate the effect of the depth of waste as an independent variable. The developed models can be used to predict calorific values of disposed MSW having similar characteristics in other landfill sites in India and abroad.


Assuntos
Modelos Estatísticos , Eliminação de Resíduos/métodos , Resíduos Sólidos/estatística & dados numéricos , Instalações de Eliminação de Resíduos/estatística & dados numéricos , Índia
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